Magnesium Cyclopentadienyl Precursors

The pyrophoric specialists — and the only non-pyrophoric alternative.

The story

Cyclopentadienyl magnesium compounds are among the most effective precursors for magnesium-containing thin film deposition. They are highly volatile, thermally stable, and strongly reactive toward co-reagents — making them the preferred choice for MOCVD and ALD of magnesium oxides, magnesium fluorides, magnesium nitrides, and magnesium-doped semiconductors.

They are also pyrophoric. They ignite spontaneously on contact with air.

Ereztech has built its magnesium precursor practice around that reality. We have purpose-built pyrophoric handling laboratories, purpose-trained staff, and purpose-designed processes for manufacturing, packaging, and shipping these materials safely at scale. Pyrophoric chemistry is not a side capability here — it is a core competency.

And for customers who need the performance of magnesium cyclopentadienyl chemistry without the pyrophoric handling burden, we developed something nobody else offers: a family of non-pyrophoric amine adduct variants, available commercially today.

The Pyrophoric Precursor Family

MgCp₂

The most widely used p-dopant for GaN-based semiconductors including GaAs, AlGaAs, and InP. Also applied for MgO buffer layers and magnesium metal film deposition. White crystalline solid, 99% purity.

Mg(MeCp)₂

Used for Mg incorporation in MOVPE GaN and growth of ZnSe, ZnSSe, and ZnMgSSe thin films. White crystalline solid, 99% purity.

Mg(EtCp)₂

Colorless to yellow liquid. Versatile reagent for advanced materials synthesis and magnesium-centered organometallic chemistry. 99% purity.

All three are manufactured under full pyrophoric safety protocols and are available in any packaging format, including custom vessel configurations for your deposition system.

The Ereztech-Developed Non-Pyrophoric Alternative

For researchers and process engineers who require the performance characteristics of magnesium cyclopentadienyl chemistry but operate without specialized pyrophoric handling infrastructure, Ereztech has developed a family of amine adduct complexes that eliminates spontaneous ignition while preserving the precursor properties that matter.

These Ereztech-developed compounds pair Mg(MeCp)₂ and Mg(EtCp)₂ with a range of diamine ligands — TMEDA, TEEDA, TMPDA, and TMBDA — yielding six distinct complexes with tunable thermal and volatility profiles. All six show clean evaporation with less than 0.5% residue above 200°C and no spontaneous ignition on air exposure. ¹H NMR, ¹³C NMR, and X-ray crystallography have verified purity and structure.

All six variants are commercially available. No other supplier offers this class of compounds.

Applications

Magnesium cyclopentadienyl precursors – pyrophoric and non-pyrophoric – are used across a growing range of thin film applications:

Semiconductor doping – p-type doping of GaN, GaAs, AlGaAs, InP, and related III-V materials for LEDs, power electronics, and RF devices

Optical coatings – magnesium fluoride thin films for anti-reflection and UV optical coatings

Electrical insulation – magnesium oxide films for dielectric and passivation layers

Energy storage – magnesium-containing films for next-generation battery and capacitor applications

Superconductor buffering – MgO as a passivating buffer layer for YBCO and REBCO deposition on semiconductor substrates

EREZTECH Applications image

Why Ereztech

Purpose-built pyrophoric capability

dedicated laboratories, trained staff, and established SOPs for manufacturing and shipping pyrophoric materials safely at a commercial scale

The only commercial source for non-pyrophoric Mg cyclopentadienyl precursors

Ereztech-developed amine adduct variants, available now, for labs and fabs without pyrophoric handling infrastructure

15+ years of metalorganic R&D and HVM

deep synthesis expertise across the cyclopentadienyl ligand family

Any packaging format

including custom vessel cleaning and reconditioning for your specific delivery system

Scale-up support

from gram quantities for feasibility through kilogram-scale HVM supply