Synonym: Tricarbonyl(cyclopentadienyl)hydridotungsten(II), CpWH(CO)3
CAS Number 12128-26-6
| Product code | W8266 |
| CAS number | 12128-26-6 |
| Assay (purity) | 98%+ |
| Purity method | by elemental analysis: %C=28.2-29.3; %H=1.8-1.9 |
| Molecular weight | 333.97 g/mol |
| Melting point | 69 °C (156 °F) |
| Form | solid |
| Appearance | white to yellow to orange to beige powder or crystals |
| Sensitivity | moisture |
| Molecular formula | C8H6O3W |
| Linear formula | C8H6O3W |
| Storage temperature | 2 – 8 °C(35.6 – 46.4 °F) |
| Packaging | glassware/metal containers/bubblers |
Cyclopentadienyltungsten(II) tricarbonyl hydride has been used as a tungsten hydride model complex with covalently attached pyridyl groups as proton acceptors. Metal hydrides are key intermediates in catalytic proton reduction and dihydrogen oxidation. There is currently much interest in appending proton relays near the metal center to accelerate catalysis by proton-coupled electron transfer (PCET). Such knowledge is crucial for rational improvements of solar fuels catalysts. See links below
Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing W8266 contact us at sales@ereztech.com
| UN | 3396 |
| Hazardous class | 4.3(4.1) |
| Packing group | III |
| Pictograms | |
| Signal word | DANGER |
| Hazard statements | H228-H261-H315-H319-H335 |
| Precautionary statements | P210-P223-P231 + P232-P240-P241-P261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P312-P334 + P335-P337 + P313-P362-P370 + P378 |
| Transport description | Organometallic substance, solid, water-reactive, flammable (Cyclopentadienyltungs ten(II) tricarbonyl hydride) |
| In TSCA registry | No (research and development usage only) |
| General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. |
| Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
| Skin contact | Wash off with soap and plenty of water. Consult a physician. |
| Inhalation | If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician. |
| If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
If you don’t see the needed lot of Cyclopentadienyltungsten(II) tricarbonyl hydride below please contact customer support at sales@ereztech.com
| Pubchem CID | 59211708 |
| IUPAC Name | 3a,4,7,7a-tetrahydro-2-benzofuran-4,7-diide-1,3-dione;tungsten(2+) |
| SMILES | [CH-]1C=C[CH-]C2C1C(=O)OC2=O.[W+2] |
| InchI Identifier | InChI=1S/C8H6O3.W/c9-7-5-3-1-2-4-6(5)8(10)11-7;/h1-6H;/q-2;+2 |
| InchI Key | GGPCPXJTVGECBL-UHFFFAOYSA-N |
Ereztech synthesizes and sells additional W-compounds.
To purchase W8266 contact us at sales@ereztech.com