Manganese carbonyl

Synonym: Decacarbonyl dimanganese, Manganese(0) Carbonyl, Dimanganese(0) decacarbonyl, Carbon monoxide – manganese (5:1)

CAS Number 10170-69-1 | MDL Number MFCD00011115  | EC Number 233-445-6

Product code	MN0691
CAS number	10170-69-1
Assay (purity)	97.5%+
Purity method	by elemental analysis: 30-31.6% (by carbon)
Molecular weight	389.98 g/mol
Form	solid
Appearance	yellow to gold to dark orange crystals or powder
Melting point	154°C (309.2°F) – decomposes
Sensitivity	air
Molecular formula	C10Mn2O10
Linear formula	Mn2(CO)10
Packaging	glassware/metal containers/bubblers

Manganese carbonyl was applied as a precursor for the growth of manganese oxide nanoparticles by a CVD process. Mn-doped AlN films (~2µ) were grown using Dimanganese decacarbonyl dopant introduced in pulsed mode (100 ms on, 100 ms off) on the top of the AlN films grown on Si(100) by MOCVD (at the same growth temperature and pressure as the AlN underlayer). This product has been applied as a dopant for the A1N films grown on silicon Si(100) substrates by MOCVD (using NH₃ and AlMe₃ sources, in V/III ratio 2.5:1).  See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing MN0691 contact us at sales@ereztech.com

Safety information

UN	3467
Hazardous class	6.1
Packing group	II
Pictograms
Signal word	DANGER
Hazard statements	H301-H311-H331
Precautionary statements	P260-P264-P271-P280-P301 + P310-P302 + P352-P304 + P340-P311-P330-P361-P363
Transport description	Organometallic compound, solid, toxic, n.o.s. (Dimanganese decacarbonyl)
In TSCA registry	Yes

First Aid Measures

General advice	Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact	Wash off with soap and plenty of water. Consult a physician.
Inhalation	If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed	Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Manganese carbonyl below please contact customer support at sales@ereztech.com

Lot# 031/374 Lot# 031/412

External identifiers for Decacarbonyl dimanganese

Pubchem CID	517769
IUPAC Name	carbon monoxide; manganese
SMILES	[Mn].[Mn].[C-]#[O+].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]
InchI Identifier	InChI=1S/10CO.2Mn/c10*1-2;;
InchI Key	QFEOTYVTTQCYAZ-UHFFFAOYSA-N

Known applications and external links

• RC Tucceri, CD Bland, ML Caldwell,  Mat. Res. Soc. Symp. Proc. Vol. 572 ° 1999 Materials Research Society, p.413-418, “SIMS and CL Characterization of Manganese-Doped Aluminum Nitride Films”
• M.L. Caldwell, H.H. Richardson and M.E. Kordesch, “Optical Properties of Manganese Doped Amorphous and Crystalline Aluminum Nitride Films”
• Hoang Anh Le, Sungmin Chin, Eunseuk Park, Le Thuy Linh, Gwi-Nam Bae, Jongsoo Jurng , Chemical Vapor Deposition, Volume 17, Issue 7-9, pages 228–234, September, 2011 , “Chemical Vapor Synthesis and Characterization of Manganese Oxides”

With Manganese carbonyl other customers often ask:

• Bis(cyclopentadienyl)manganese
• Bis(ethylcyclopentadienyl)manganese
• Bis(isopropylcyclopentadienyl)manganese
• Manganese(II) acetylacetonate

Ereztech synthesizes and sells additional MN-compounds.

To purchase MN0691 contact us at sales@ereztech.com