Nickel(II) 1-dimethylamino-2-methyl-2-butoxide

Synonym: Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II), bis(1- dimethylamino-2-methyl-2-butoxide)nickel(II), Ni(dmamb)₂, MABONi

CAS Number 942311-35-5 

Product code	NI1355
CAS number	942311-35-5
Assay (purity)	98%+
Purity method	by elemental analysis: %C=51.6-53.7; %H=9.9-10.3
NMR H1	conforms to structure
Molecular weight	542.04 g/mol
Melting point	<10 °C
Boiling point	148 °C at 3.32 Torr
Form	liquid
Appearance	dark green viscous liquid
Sensitivity	air, moisture
Molecular formula	C14H32N2O2Ni
Linear formula	C14H32N2O2Ni
Packaging	glassware/metal containers/bubblers

Nickel(II) 1-dimethylamino-2-methyl-2-butoxide with water and hydrogen sulfide as oxygen and sulfur sources were employed in the atomic layer deposition of nickel oxide and nickel sulfide thin films. Due to its volatility and liquid state at RT, this product is promising as a precursor for the growth of Ni-containing layers by MOCVD and ALD. Ni(dmamb)₂ was employed as a precursor for the growth of nickel oxide NiO films on Si and Pt/SiO₂/Si substrates at 230–410°C temperatures by cold-wall low-pressure MOCVD. The I–V measurements of NiO films grown using this product revealed an interesting switching behavior of the NiO films having low and high resistance states, suggesting their applicability as ReRAM devices. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing NI1355 contact us at sales@ereztech.com

Safety information

UN	3398
Hazardous class	4.3
Packing group	II
Pictograms
Signal word	DANGER
Hazard statements	H315-H319-H334-H335-H372
Precautionary statements	P260-P264-P270-P271-P280-P285-P302 + P352-P304 + P340-P305 + P351 + P338-P311 + P342-P312-P314-P332 + P313-P337 + P313-P362
Transport description	Organometallic substance, liquid, water-reactive, (Nickel(II) 1- dimethylamino-2- methyl-2-butoxide)
In TSCA registry	No (research and development usage only)

First Aid Measures

General advice	Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact	Wash off with soap and plenty of water. Consult a physician.
Inhalation	If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed	Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Nickel(II) 1-dimethylamino-2-methyl-2-butoxide below please contact customer support at sales@ereztech.com

lot# 015/789 Lot# 015/817 Lot# 015/885

External identifiers for MABONi

Pubchem CID	89558561
IUPAC Name	1-(dimethylamino)-2-methylbutan-2-olate;nickel(2+)
SMILES	CCC(C)(CN(C)C)[O-].CCC(C)(CN(C)C)[O-].[Ni+2]
InchI Identifier	InChI=1S/2C7H16NO.Ni/c2*1-5-7(2,9)6-8(3)4;/h2*5-6H2,1-4H3;/q2*-1;+2
InchI Key	LECAMOYWYJUYIH-UHFFFAOYSA-N

Known applications and external links

• Myeong-Hee Ko, Bonggeun Shong, Jin-Ha Hwang. Low Temperature Atomic Layer Deposition of Nickel Sulfide and Nickel Oxide Thin Films Using Ni(dmamb)2 as Ni Precursor. Ceramics International 44(14):16342-16351 · October 2018
• K.-C. Min, M. Kim, Y.-H. You, S.S. Lee, Y.K. Lee, T.-M. Chung, C.G. Kim, J.-H. Hwang, K.-S. An, N.-S. Lee, Y. Kim, Surf. Coat. Tech., 2007, Vol. 201, Iss. 22–23, p.9252-9255. NiO thin films by MOCVD of Ni(dmamb)2 and their resistance switching phenomena

With Nickel(II) 1-dimethylamino-2-methyl-2-butoxide other customers often ask:

• Bis(ethylcyclopentadienyl)nickel
• (1,2-Bis(diphenylphosphino)ethane)dichloronickel(II)
• Allyl(cyclopentadienyl)nickel (II)
• Bis(tricyclohexylphosphine)nickel(II) chloride

Ereztech synthesizes and sells additional NI-compounds.

To purchase NI1355 contact us at sales@ereztech.com