Zirconium tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionate)

Synonym: Tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)zirconium, Zirconium tetrakis(dipivaloylmethanate), Zr(TMHD)4

CAS Number 18865-74-2 | MDL Number MFCD00145380 

Zr(TMHD)4 chemical structure

Product codeZR5742
CAS number18865-74-2
Assay (purity)98%
Purity methodby elemental analysis: %C = 62.5 – 65.7; %H = 9.1 – 9.5%
Molecular weight824.30 g/mol
Melting point332 – 339 °C (630 – 642 °F)
Boiling point180 °C (356 °F) @ 0.1 mm Hg – sublimation
Formsolid
Appearancewhite powder or crystals
Sensitivitymoisture
Molecular formulaC44H76O8Zr
Linear formulaZr(C11H19O2)4
Packagingglassware/metal containers/bubblers

Zirconium tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionate) and Yttrium tris(2,2,6,6-tetramethyl-3,5-heptanedionato) dipivaloylmethanates were used as precursors for film deposition by the method of chemical deposition from the gas phase of organometallic compounds (CVDOM) to obtain thin electrolyte films of zirconia stabilized by yttria (YSZ) on a supporting electrode. Gas-tight electrolyte films were obtained on a supporting anode with a thickness of 4–10 μm at moderate deposition temperatures of 500–700°C. See link below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing ZR5742 contact us at sales@ereztech.com

Safety information

UNNot regulated
Hazardous classNot regulated
Packing groupNot regulated
PictogramsGHS07
Signal wordWARNING
Hazard statementsH315-H319-H335
Precautionary statementsP261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P312-P332 + P313-P337 + P313-P362
Transport descriptionNONH for all modes of transport
In TSCA registryNo (research and development usage only)

First Aid Measures

General adviceConsult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contactWash off with soap and plenty of water. Consult a physician.
InhalationIf breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Zirconium tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionate) below please contact customer support at sales@ereztech.com

Lot# 015/353

External identifiers for Zr(TMHD)4

Pubchem CID6287074
IUPAC Name(Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one;zirconium
SMILESCC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.[Zr]
InchI IdentifierInChI=1S/4C11H20O2.Zr/c4*1-10(2,3)8(12)7-9(13)11(4,5)6;/h4*7,12H,1-6H3;/b4*8-7-;
InchI KeyANBXKEDJQLYCLX-DNSQIVDOSA-N

Known applications and external links

With Zirconium tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionate) other customers often ask:

Ereztech synthesizes and sells additional ZR-compounds.

To purchase ZR5742 contact us at sales@ereztech.com