Cobalt, tricarbonyl(h3-2-propenyl)

Synonym: p-Allylcobalt tricarbonyl, Tricarbonyl-p-allylcobalt, (h3-allyl)tricarbonylcobalt, Allyltricarbonylcobalt, Tricarbonyl allyl cobalt

CAS Number 12144-85-3 | EC Number 806-367-0

Product code	CO4853
CAS number	12144-85-3
Assay (purity)	97%+
Purity method	by integration NMR H1
NMR H1	conforms to structure
Molecular weight	184.0353 g/mol
Boiling point	39 °C (102.2 °F) @ 15 mmHg
Form	liquid
Appearance	red to dark red liquid
Sensitivity	air
Molecular formula	C6H5CoO3
Linear formula	(C3H6)Co(C0)3
Packaging	glassware/metal containers/bubblers

Cobalt, tricarbonyl(h3-2-propenyl) was synthesized as potential MOCVD precursor, together with other allyl cobalt complexes. The synthesis of this product is described in the literature. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing CO4853 contact us at sales@ereztech.com

Safety information

UN	1992
Hazardous class	3 (6.1)
Packing group	III
Pictograms
Signal word	DANGER
Hazard statements	H226-H301-H311-H317-H331-H334-H341-H351-H413
Precautionary statements	P201-P202-P210-P233-P240-P241-P242-P243-P261-P264-P270-P271-P272-P273-P280-P285-P301 + P310-P302 + P352-P303 + P361 + P353-P304 + P340-P308 + P313-P311-P333 + P313-P342 + P311-P363-P370 + P378
Transport description	Flammable liquid, toxic, n.o.s. (Cobalt, tricarbonyl(h3-2- propenyl))
In TSCA registry	No (research and development usage only)

First Aid Measures

General advice	Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact	Wash off with soap and plenty of water. Consult a physician.
Inhalation	If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed	Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Cobalt, tricarbonyl(h3-2-propenyl) below please contact customer support at sales@ereztech.com

Lot# 006/575

External identifiers for Allyltricarbonylcobalt

Pubchem CID	135094398
SMILES	C1C2C[Co]12(C#[OH])(C#[OH])C#[OH]
InchI Identifier	InChI=1S/C3H5.3CHO.Co/c1-3-2;3*1-2;/h3H,1-2H2;3*2H;
InchI Key	VWEYORAUTMIOLH-UHFFFAOYSA-N

Known applications and external links

• Richard F. Heck, David S. Breslow. Alkyl- and Acyl-cobalt Carbonyls Containing Olefinic Unsaturation. Allylcobalt Tricarbonyl and Related Compounds
• Gábor Szalontai, Judit Sóvágó, Ferenc Ungvárybc. Solution- and solid-state NMR study of intermediate η3-allyl-cobalt tricarbonyl type complexes in 3-methyl-1,2-butadiene polymerization
• Ron S. Dickson, Ping Yin, Mingzhe Ke, Julian Johnson, Glen B. Deacon. The assessment of some cobalt and cobalt-tellurium complexes for MOCVD applications

With Cobalt, tricarbonyl(h3-2-propenyl) other customers often ask:

• Bis(N,N-di-tert-butyl-1,4-diaza-1,3-butadienyl)cobalt
• Cobalt tricarbonyl nitrosyl
• Dicobalt Octacarbonyl (stabilised with 1-5% Hexane)
• Dicarbonylcyclopentadienylcobalt

Ereztech synthesizes and sells additional CO-compounds.

To purchase CO4853 contact us at sales@ereztech.com