Synonym: Ytterbium(III)-DPM, Yb(TMHD)3
CAS Number 15492-52-1 | MDL Number MFCD00000034
Product code | YB2521 |
CAS number | 15492-52-1 |
Assay (purity) | 99% |
Metal purity | 99.9%-Yb |
Purity method | by titration: %Yb = 23.6 – 24.3 % (complexometric) |
Molecular weight | 722.84 g/mol |
Melting point | 167-169 °C (333-336 °F) |
Boiling point | 300 °C (572 °F) |
Form | solid |
Appearance | off-white powder or crystals |
Sensitivity | moisture |
Molecular formula | YbC33H57O6 |
Linear formula | Yb[OCC(CH3)3CHCOC(CH3)3]3 |
Packaging | glassware/metal containers/bubblers |
2,2,6,6-Tetramethyl-3,5-heptanedionate ytterbium, also referred to as Ytterbium(III)-DPM or Yb(TMHD)₃, is an organoytterbium compound with the molecular formula C₃₃H₅₇O₆Yb and a molecular weight of 722.84 g/mol. This compound features ytterbium in a +3 oxidation state, coordinated with three 2,2,6,6-tetramethyl-3,5-heptanedionate ligands, providing a stable framework that supports various deposition processes. Typically appearing as an off-white powder or crystalline solid, it has a high purity of 99%, verified by titration, and an ytterbium content between 23.3-24.5%, confirmed through complexometric analysis.
2,2,6,6-Tetramethyl-3,5-heptanedionate ytterbium is widely employed in thin-film deposition techniques, such as metal-organic chemical vapor deposition (MOCVD) and atomic layer deposition (ALD), where its stability and high purity are critical for producing ytterbium-based films. This compound is particularly valuable in semiconductor and optical applications, where precise ytterbium incorporation enhances the properties of the deposited films. Its structure, featuring bulky heptanedionate ligands, allows for controlled reactivity, making it suitable for applications in material science and advanced ceramics.
Although not classified under specific hazard codes, standard laboratory precautions should be observed when handling 2,2,6,6-tetramethyl-3,5-heptanedionate ytterbium. Proper storage in a dry, cool environment, ideally in tightly sealed containers, is essential to prevent any potential degradation. Its relatively high melting point of 167-169°C and boiling point of around 300°C indicate stability under standard handling conditions. However, protective gear, including gloves and eye protection, is recommended during handling to avoid skin and eye irritation.
In both industrial and laboratory contexts, 2,2,6,6-Tetramethyl-3,5-heptanedionate ytterbium is integral to the production of thin films and specialized coatings, particularly in the fabrication of optical devices and electronic components. Its high-purity composition and stability facilitate precise ytterbium deposition, ensuring uniform, durable coatings that enhance performance in advanced technological applications. The compound’s ability to form stable, ytterbium-rich films supports research and development in areas requiring precise control over material composition and properties, advancing innovations in the electronics and materials science sectors.
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium possess the useful property of inducing large chemical shifts in the proton NMR spectra of certain compounds containing OH or other nucleophilic groups 1–8. The synthesis of this product is described in the literature. See links below
Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing YB2521 contact us at sales@ereztech.com
UN | Not regulated |
Hazardous class | Not regulated |
Packing group | Not regulated |
Pictograms | |
Signal word | WARNING |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P312-P332 + P313-P337 + P313-P362 |
Transport description | NONH for all modes of transport |
In TSCA registry | Yes |
General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. |
Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
Skin contact | Wash off with soap and plenty of water. Consult a physician. |
Inhalation | If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician. |
If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
If you don’t see the needed lot of Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)ytterbium below please contact customer support at sales@ereztech.com
Pubchem CID | 11787441 |
IUPAC Name | (Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one;ytterbium |
SMILES | CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.CC(C)(C)C(=CC(=O)C(C)(C)C)O.[Yb] |
InchI Identifier | InChI=1S/3C11H20O2.Yb/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/b3*8-7-; |
InchI Key | HIZKKNPMYSUCGY-LWTKGLMZSA-N |
Ereztech synthesizes and sells additional YB-compounds.
To purchase YB2521 contact us at sales@ereztech.com