Bis(acetato-O)triphenylbismuth(V)
Synonym: Diacetoxytriphenylbismuth, Triphenylbismuth diacetate, Bis triphenylbismuth
CAS Number 7239-60-3 | MDL Number MFCD00092697
Bis(acetato-O)triphenylbismuth(V) is one of the Bismuth Aryls. Bismuth Aryls are useful reagent, catalyst, and precursor materials with applications in MOCVD, due to their volatility and air stability. Arylbismuth compounds are effective reagents for the O-arylation of alcohols, phenols, and other oxygen nucleophiles. See links below
Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing Bis(acetato-O)triphenylbismuth(V) contact us at sales@ereztech.com
Safety information
| UN | Not regulated |
| Signal word | No signal word |
| Hazard statements | No known significant effects or critical hazards |
| Transport description | NONH for all modes of transport |
| In TSCA registry | No (sold for research and development usage only) |
First Aid Measures
| General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. |
| Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
| Skin contact | Wash off with soap and plenty of water. Consult a physician. |
| Inhalation | If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician. |
| If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
Certificates of Analysis (CoA)
If you don’t see the needed lot of Bis(acetato-O)triphenylbismuth(V) below please contact customer support at sales@ereztech.com
External identifiers for Diacetoxytriphenylbismuth
| Pubchem CID | 16684857 |
| SMILES | CC(=O)O[Bi](C1=CC=CC=C1)(C2=CC=CC=C2)(C3=CC=CC=C3)OC(=O)C |
| IUPAC Name | diacetyloxy(triphenyl)bismuth |
| InchI Identifier | InChI=1S/3C6H5.2C2H4O2.Bi/c3*1-2-4-6-5-3-1;2*1-2(3)4;/h3*1-5H;2*1H3,(H,3,4);/q;;;;;+2/p-2 |
| InchI Key | UXYBKDNBDQNDNV-UHFFFAOYSA-L |
Known applications and external links
- J.-P. FinetA. Yu. Fedorov Synthesis and reactivity of chiral pentavalent bismuth derivatives. Russian Chemical Bulletin July 2004, Volume 53, Issue 7, pp 1488–1495
- Gagnon, A.; Benoit, E.; Le Roch, A. O-Arylation Reactions. Science of Synthesis Knowledge Updates, (2018) 4, 69.
With Bis(acetato-O)triphenylbismuth(V) other customers often ask:
- Tributylbismuthine
- Tris(2-metoxyphenyl)bismuthine
- 2,2,6,6-Tetramethyl-3,5-heptanedionate(III)bismuthine
- Bismuth (III) Bromide
Ereztech synthesizes and sells additional BI-compounds.
To purchase Bis(acetato-O)triphenylbismuth(V) contact us at sales@ereztech.com
