Bromopentacarbonylmanganese(I)

Synonym: Pentacarbonylbromomanganese(I), Manganese pentacarbonyl bromide, Carbon monooxide-bromomanganese (5:1)

CAS Number 14516-54-2 | MDL Number MFCD00049806  | EC Number 238-522-8

Manganese pentacarbonyl bromide Chemical Structure

Product code MN6542
CAS number 14516-54-2
Assay (purity) 97.5%+
Purity method by titration: 97.5-102.5% with AgNO3
Molecular weight 274.89 g/mol
Form solid
Appearance light orange to very dark orange powder or crystals
Sensitivity air, moisture, store cold
Molecular formula BrC5O5Mn
Linear formula BrMn(CO)5
Packaging glassware/metal containers/bubblers

Bromopentacarbonylmanganese(I) is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene, and toluene) in the presence silver salt. Also, this product was proposed as a potential Mn precursor for the growth of ZnS: Mn phosphor layers suitable for use in thin-film electroluminescent components by the ALE method. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing MN6542 contact us at sales@ereztech.com

Safety information

UN Not regulated
Hazardous class Not regulated
Packing group Not regulated
Pictograms  GHS07
Signal word WARNING
Hazard statements H302 + H312 + H332
Precautionary statements P261-P264-P271-P280P301 + P312-P302 + P352-P304 + P340-P312-P322-P330-P363
Transport description NONH for all modes of transport
In TSCA registry No (research and development usage only)

First Aid Measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off with soap and plenty of water. Consult a physician.
Inhalation If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Certificates of Analysis (CoA)

If you don’t see the needed lot of Bromopentacarbonylmanganese(I) below please contact customer support at sales@ereztech.com

Lot# 031/380 Lot# 031/376 Lot# 031/356 Lot# 031/332 Lot# 031/347 Lot# 031/403 Lot# 031/413

External identifiers for Pentacarbonylbromomanganese(I)

Pubchem CID 10978692
IUPAC Name bromo-pentakis(oxomethyl)manganese
SMILES [C](=O)[Mn]([C]=O)([C]=O)([C]=O)([C]=O)Br
InchI Identifier InChI=1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
InchI Key OESORJHGSXJTKX-UHFFFAOYSA-M

Known applications and external links

With Bromopentacarbonylmanganese(I) oxide other customers often ask:

Ereztech synthesizes and sells additional MN-compounds.

To purchase MN6542 contact us at sales@ereztech.com