Cobalt, tricarbonyl(h3-2-propenyl)
Synonym: p-Allylcobalt tricarbonyl, Tricarbonyl-p-allylcobalt, (h3-allyl)tricarbonylcobalt, Allyltricarbonylcobalt, Tricarbonyl allyl cobalt
CAS Number 12144-85-3 | EC Number 806-367-0
Product code | CO4853 |
CAS number | 12144-85-3 |
Assay (purity) | 97%+ |
Purity method | by integration NMR H1 |
NMR H1 | conforms to structure |
Molecular weight | 184.0353 g/mol |
Boiling point | 39 °C (102.2 °F) @ 15 mmHg |
Form | liquid |
Appearance | red to dark red liquid |
Sensitivity | air |
Molecular formula | C6H5CoO3 |
Linear formula | (C3H6)Co(C0)3 |
Packaging | glassware/metal containers/bubblers |
Cobalt, tricarbonyl(h3-2-propenyl) was synthesized as potential MOCVD precursor, together with other allyl cobalt complexes. The synthesis of this product is described in the literature. See links below
Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing CO4853 contact us at sales@ereztech.com
Safety information
UN | 1992 |
Hazardous class | 3 (6.1) |
Packing group | III |
Pictograms | |
Signal word | DANGER |
Hazard statements | H226-H301-H311-H317-H331-H334-H341-H351-H413 |
Precautionary statements | P201-P202-P210-P233-P240-P241-P242-P243-P261-P264-P270-P271-P272-P273-P280-P285-P301 + P310-P302 + P352-P303 + P361 + P353-P304 + P340-P308 + P313-P311-P333 + P313-P342 + P311-P363-P370 + P378 |
Transport description | Flammable liquid, toxic, n.o.s. (Cobalt, tricarbonyl(h3-2- propenyl)) |
In TSCA registry | No (research and development usage only) |
First Aid Measures
General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. |
Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
Skin contact | Wash off with soap and plenty of water. Consult a physician. |
Inhalation | If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician. |
If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
Certificates of Analysis (CoA)
If you don’t see the needed lot of Cobalt, tricarbonyl(h3-2-propenyl) below please contact customer support at sales@ereztech.com
External identifiers for Allyltricarbonylcobalt
Pubchem CID | 135094398 |
SMILES | C1C2C[Co]12(C#[OH])(C#[OH])C#[OH] |
InchI Identifier | InChI=1S/C3H5.3CHO.Co/c1-3-2;3*1-2;/h3H,1-2H2;3*2H; |
InchI Key | VWEYORAUTMIOLH-UHFFFAOYSA-N |
Known applications and external links
- Richard F. Heck, David S. Breslow. Alkyl- and Acyl-cobalt Carbonyls Containing Olefinic Unsaturation. Allylcobalt Tricarbonyl and Related Compounds
- Gábor Szalontai, Judit Sóvágó, Ferenc Ungvárybc. Solution- and solid-state NMR study of intermediate η3-allyl-cobalt tricarbonyl type complexes in 3-methyl-1,2-butadiene polymerization
- Ron S. Dickson, Ping Yin, Mingzhe Ke, Julian Johnson, Glen B. Deacon. The assessment of some cobalt and cobalt-tellurium complexes for MOCVD applications
With Cobalt, tricarbonyl(h3-2-propenyl) other customers often ask:
- Bis(N,N-di-tert-butyl-1,4-diaza-1,3-butadienyl)cobalt
- Cobalt tricarbonyl nitrosyl
- Dicobalt Octacarbonyl (stabilised with 1-5% Hexane)
- Dicarbonylcyclopentadienylcobalt
Ereztech synthesizes and sells additional CO-compounds.
To purchase CO4853 contact us at sales@ereztech.com