Gadolinium(III) isopropoxide

Synonym: Tris(isopropoxy) gadolinium(III), Gadolinium(III) i-propoxide 

CAS Number 14532-05-9 | MDL Number MFCD00144381 | EC Number 621-418-5

Gadolinium(III) isopropoxide Chemical Structure

Product codeGD2059
CAS number14532-05-9
Assay (purity)99%
Metal purity99.9%-Gd
Purity methodby titration: %Gd 46.3 – 47.7% (complexometric)
Molecular weight334.51 g/mol
Formsolid
Appearancewhite to off-white powder
Melting point>300 °C (572 °F)
Sensitivitymoisture
Molecular formulaGdC9H21O3
Linear formulaGdC9H21O3
Packagingglassware/metal containers/bubblers

Gadolinium(III) isopropoxide has been used as a catalyst for enantioselective construction of beta-quaternary carbons via conjugate addition reactions, generation of reactive enolates, regioselective/stereoselective conjugate addition of cyanide to enones, Strecker reactions, asymmetric ring-opening of Meso-aziridines. 

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing Gadolinium(III) isopropoxide contact us at sales@ereztech.com

Safety information

UNNot regulated
Hazardous classNot regulated
Packing groupNot regulated
PictogramsGHS07
Signal wordWARNING
Hazard statementsH315-H319-H335
Precautionary statementsP261-P264-P271-P280-P302 + P352-P305 + P351 + P338-P312-P332 + P313-P337 + P313-P362
Transport descriptionNONH for all modes of transport
In TSCA registryNo (sold for research and development usage only)

First Aid Measures

General adviceConsult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contactWash off with soap and plenty of water. Consult a physician.
InhalationIf breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Certificates of Analysis (CoA)

If you don’t see the needed lot of Gadolinium(III) isopropoxide below please contact customer support at sales@ereztech.com

Lot# 003/537

External identifiers for Tris(isopropoxy) gadolinium(III)

Pubchem CID15047187
SMILESCC(C)[O-].CC(C)[O-].CC(C)[O-].[Gd+3]
IUPAC NameStannic Tetraacetate
InchI IdentifierInChI=1S/3C3H7O.Gd/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InchI KeyVJLSFXQJAXVOEQ-UHFFFAOYSA-N

With Gadolinium(III) isopropoxide other customers often ask:

Ereztech synthesizes and sells additional GD-compounds.

To purchase Gadolinium(III) isopropoxide contact us at sales@ereztech.com