Gadolinium(III) isopropoxide

Synonym: Tris(isopropoxy) gadolinium(III), Gadolinium(III) i-propoxide 

CAS Number 14532-05-9 | MDL Number MFCD00144381 | EC Number 621-418-5

Gadolinium(III) isopropoxide Chemical Structure

Product code GD2059
CAS number 14532-05-9
Assay (purity) 99%
Metal purity 99.9%-Gd
Purity method by titration: %Gd 46.3 – 47.7% (complexometric)
Molecular weight 334.51 g/mol
Form solid
Appearance white to off-white powder
Melting point >300 °C (572 °F)
Sensitivity moisture
Molecular formula GdC9H21O3
Linear formula GdC9H21O3
Packaging glassware/metal containers/bubblers

Gadolinium(III) isopropoxide has been used as a catalyst for enantioselective construction of beta-quaternary carbons via conjugate addition reactions, generation of reactive enolates, regioselective/stereoselective conjugate addition of cyanide to enones, Strecker reactions, asymmetric ring-opening of Meso-aziridines. 

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing Gadolinium(III) isopropoxide contact us at sales@ereztech.com

Safety information

UN Not regulated
Hazardous class Not regulated
Packing group Not regulated
Pictograms GHS07
Signal word WARNING
Hazard statements H315-H319-H335
Precautionary statements P261-P264-P271-P280-P302 + P352-P305 + P351 + P338-P312-P332 + P313-P337 + P313-P362
Transport description NONH for all modes of transport
In TSCA registry No (sold for research and development usage only)

First Aid Measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off with soap and plenty of water. Consult a physician.
Inhalation If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Certificates of Analysis (CoA)

If you don’t see the needed lot of Gadolinium(III) isopropoxide below please contact customer support at sales@ereztech.com

Lot# 003/537

External identifiers for Tris(isopropoxy) gadolinium(III)

Pubchem CID 15047187
SMILES CC(C)[O-].CC(C)[O-].CC(C)[O-].[Gd+3]
IUPAC Name gadolinium(3+);propan-2-olate
InchI Identifier InChI=1S/3C3H7O.Gd/c3*1-3(2)4;/h3*3H,1-2H3;/q3*-1;+3
InchI Key VJLSFXQJAXVOEQ-UHFFFAOYSA-N

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Ereztech synthesizes and sells additional GD-compounds.

To purchase Gadolinium(III) isopropoxide contact us at sales@ereztech.com