Methylcyclopentadienyltungsten tricarbonyl hydride

Synonym: (MeCp)WH(CO)₃

Product code	W0003
CAS number	N/A
Assay (purity)	99%+
Purity method	by integration NMR H1
NMR H1	conforms to structure
Molecular weight	349.01 g/mol
Form	solid
Appearance	pale yellow crystals
Sensitivity	moisture, heat, light
Molecular formula	C9H9O3W
Packaging	glassware/metal containers/bubblers

Methylcyclopentadienyltungsten tricarbonyl hydride has been used as proxy catalysts, with covalently attached pyridyl groups as proton acceptors. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing W0003 contact us at sales@ereztech.com

Safety information

UN	3396
Hazardous class	4.3(4.1)
Packing group	III
Pictograms
Signal word	DANGER
Hazard statements	H228-H261-H301-H311-H315-H319-H331-H335
Precautionary statements	P210-P231 + P232-P240-P241-P261-P264-P270-P271-P280-P301 + P310-P302 + P352-P304 + P340-P305 + P351 + P338-P310-P330-P332 + P313-P361-P363-P370 + P378
Transport description	Organometallic substance, solid, water-reactive, flammable (Methylcyclopenta- dienyltungsten tricarbonyl hydride)
In TSCA registry	No (research and development usage only)

First Aid Measures

General advice	Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact	Wash off with soap and plenty of water. Consult a physician.
Inhalation	If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed	Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Methylcyclopentadienyltungsten tricarbonyl hydride below please contact customer support at sales@ereztech.com

Lot# 017/239

Known applications and external links

• Tianfei Liu, Andreas Orthaber, Marcus Lundberg, Leif Hammarström, Meiyuan Guo, Reiner Lomoth, Sascha Ott Accelerating proton-coupled electron transfer of metal hydrides in catalyst model reactions

With Methylcyclopentadienyltungsten tricarbonyl hydride other customers often ask:

• Tungsten hexacarbonyl
• Bis(isopropylcyclopentadienyl)tungsten(IV) dihydride
• Tungsten(VI) ethoxide
• Bis(tert-butylimino)bis(dimethylamino)tungsten(VI)

Ereztech synthesizes and sells additional W-compounds.

To purchase W0003 contact us at sales@ereztech.com