Synonym: Tungsten carbonyl, Hexacarbonyl wolfram, W(CO)6
CAS Number 14040-11-0 | MDL Number MFCD00011462 | EC Number 237-880-2
Tungsten hexacarbonyl is easily vaporized and decomposed by the electron beam — providing a convenient source of tungsten atoms. This product is widely used in electron beam-induced deposition processes, it is also used as a precursor to catalysts for alkene metathesis and to desulfurize organosulfur compounds. It is relatively air-stable, and it is sparingly soluble in non-polar organic solvents. W(CO)6 reactions begin with the displacement of some of its CO ligands. Similar to Mo(CO)6 in behavior, W(CO)6 typically forms compounds that are kinetically more robust. Synthesis of this product are reported (see the links below).
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|In TSCA registry||Yes|
First Aid Measures
|General advice||Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.|
|Eye contact||Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.|
|Skin contact||Wash off with soap and plenty of water. Consult a physician.|
|Inhalation||If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.|
|If swallowed||Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.|
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External identifiers for Hexacarbonylwolfram
Known applications and external links
- Manning, A. R.; Hacket, Paul; Birdwhistell, Ralph (1990). “Hexacarbonylbis(η5‐Cyclopentadienyl)Dichromium, Molybdenum, and Tungsten and their Analogs, M2(η5‐C5H4R)2(CO)6 (M = Cr, Mo, and W; R = H, Me or PhCH2)”. Inorganic Syntheses. 28: 148–149.
- Kubas, G. J.; van der Sluys, L. S. (1990). “TricarbonylTris(nitrile) Complexes of Cr, Mo, and W”. Inorganic Syntheses. 28: 29–33.
With Tungsten hexacarbonyl other customers often ask:
- Tungsten(VI) ethoxide
- tris(3-hexyne)tungsten(0) carbonyl
- Bis(cyclopentadienyl)tungsten dichloride
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