Nickel(II) 1-dimethylamino-2-methyl-2-butoxide

Synonym: Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II), bis(1- dimethylamino-2-methyl-2-butoxide)nickel(II), Ni(dmamb)2, MABONi

CAS Number 942311-35-5 

Product codeNI1355
CAS number942311-35-5
Assay (purity)98%+
Purity methodby elemental analysis: %C=51.6-53.7; %H=9.9-10.3
NMR H1conforms to structure
Molecular weight542.04 g/mol
Melting point<10 °C (<50 °F)
Boiling point148 °C (298.4 °F) at 3.32 Torr
Formliquid
Appearancedark green liquid
Sensitivitymoisture
Molecular formulaC14H32N2O2Ni
Linear formulaC14H32N2O2Ni
Packagingglassware/metal containers/bubblers

Nickel(II) 1-dimethylamino-2-methyl-2-butoxide with water and hydrogen sulfide as oxygen and sulfur sources were employed in the atomic layer deposition of nickel oxide and nickel sulfide thin films. Due to its volatility and liquid state at RT, this product is promising as a precursor for the growth of Ni-containing layers by MOCVD and ALD. Ni(dmamb)2 was employed as a precursor for the growth of nickel oxide NiO films on Si and Pt/SiO2/Si substrates at 230–410°C temperatures by cold-wall low-pressure MOCVD. The I–V measurements of NiO films grown using this product revealed an interesting switching behavior of the NiO films having low and high resistance states, suggesting their applicability as ReRAM devices. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing NI1355 contact us at sales@ereztech.com

Safety information

UN3398
Hazardous class4.3
Packing groupII
PictogramsGHS08 GHS07
Signal wordDANGER
Hazard statementsH315-H319-H334-H335-H372
Precautionary statementsP260-P264-P270-P271-P280-P285-P302 + P352-P304 + P340-P305 + P351 + P338-P311 + P342-P312-P314-P332 + P313-P337 + P313-P362
Transport descriptionOrganometallic substance, liquid, water-reactive, (Nickel(II) 1- dimethylamino-2- methyl-2-butoxide)
In TSCA registryNo (research and development usage only)

First Aid Measures

General adviceConsult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contactWash off with soap and plenty of water. Consult a physician.
InhalationIf breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Nickel(II) 1-dimethylamino-2-methyl-2-butoxide below please contact customer support at sales@ereztech.com

Lot# 015/817 lot# 015/789

External identifiers for MABONi

Pubchem CID89558561
IUPAC Name1-(dimethylamino)-2-methylbutan-2-olate;nickel(2+)
SMILESCCC(C)(CN(C)C)[O-].CCC(C)(CN(C)C)[O-].[Ni+2]
InchI IdentifierInChI=1S/2C7H16NO.Ni/c2*1-5-7(2,9)6-8(3)4;/h2*5-6H2,1-4H3;/q2*-1;+2
InchI KeyLECAMOYWYJUYIH-UHFFFAOYSA-N

Known applications and external links

With Nickel(II) 1-dimethylamino-2-methyl-2-butoxide other customers often ask:

Ereztech synthesizes and sells additional NI-compounds.

To purchase NI1355 contact us at sales@ereztech.com