Nickel(II) 1-dimethylamino-2-methyl-2-butoxide

Synonym: Bis(1-dimethylamino-2-methyl-2-butoxy)nickel(II), bis(1- dimethylamino-2-methyl-2-butoxide)nickel(II), Ni(dmamb)2, MABONi

CAS Number 942311-35-5 

Product code NI1355
CAS number 942311-35-5
Assay (purity) 98%+
Purity method by elemental analysis: %C=51.6-53.7; %H=9.9-10.3
NMR H1 conforms to structure
Molecular weight 542.04 g/mol
Melting point <10 °C
Boiling point 148 °C at 3.32 Torr
Form liquid
Appearance dark green viscous liquid
Sensitivity air, moisture
Molecular formula C14H32N2O2Ni
Linear formula C14H32N2O2Ni
Packaging glassware/metal containers/bubblers

Nickel(II) 1-dimethylamino-2-methyl-2-butoxide with water and hydrogen sulfide as oxygen and sulfur sources were employed in the atomic layer deposition of nickel oxide and nickel sulfide thin films. Due to its volatility and liquid state at RT, this product is promising as a precursor for the growth of Ni-containing layers by MOCVD and ALD. Ni(dmamb)2 was employed as a precursor for the growth of nickel oxide NiO films on Si and Pt/SiO2/Si substrates at 230–410°C temperatures by cold-wall low-pressure MOCVD. The I–V measurements of NiO films grown using this product revealed an interesting switching behavior of the NiO films having low and high resistance states, suggesting their applicability as ReRAM devices. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing NI1355 contact us at sales@ereztech.com

Safety information

UN 3398
Hazardous class 4.3
Packing group II
Pictograms GHS08 GHS07
Signal word DANGER
Hazard statements H315-H319-H334-H335-H372
Precautionary statements P260-P264-P270-P271-P280-P285-P302 + P352-P304 + P340-P305 + P351 + P338-P311 + P342-P312-P314-P332 + P313-P337 + P313-P362
Transport description Organometallic substance, liquid, water-reactive, (Nickel(II) 1- dimethylamino-2- methyl-2-butoxide)
In TSCA registry No (research and development usage only)

First Aid Measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off with soap and plenty of water. Consult a physician.
Inhalation If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Nickel(II) 1-dimethylamino-2-methyl-2-butoxide below please contact customer support at sales@ereztech.com

lot# 015/789 Lot# 015/817 Lot# 015/885

External identifiers for MABONi

Pubchem CID 89558561
IUPAC Name 1-(dimethylamino)-2-methylbutan-2-olate;nickel(2+)
SMILES CCC(C)(CN(C)C)[O-].CCC(C)(CN(C)C)[O-].[Ni+2]
InchI Identifier InChI=1S/2C7H16NO.Ni/c2*1-5-7(2,9)6-8(3)4;/h2*5-6H2,1-4H3;/q2*-1;+2
InchI Key LECAMOYWYJUYIH-UHFFFAOYSA-N

Known applications and external links

With Nickel(II) 1-dimethylamino-2-methyl-2-butoxide other customers often ask:

Ereztech synthesizes and sells additional NI-compounds.

To purchase NI1355 contact us at sales@ereztech.com