Tetra-t-butoxide tungsten oxide CAS 58832-09-0

Tetra-t-butoxide tungsten oxide

Synonym: WO(O-t-Bu)4, Tetrakis(2-methyl-2-propanolato)oxotungsten

CAS Number 58832-09-0 

Product code W2090
CAS number 58832-09-0
Assay (purity) 97.5%+
Purity method by elemental analysis (%C = 38,1 – 40,0; %H = 7,2 – 7,6 %)
NMR conforms to structure
Molecular weight 492.31 g/mol
Form solid
Appearance white crystals
Boiling point 60 oC/0,01 Torr (sublim.)
Sensitivity air, moisture
Molecular formula C16H36O5W
Linear formula [OC(CH3)3]4W(O)
Packaging glassware/metal containers/bubblers

Tetra-t-butoxide tungsten oxide, also known as WO(O-t-Bu)₄ or Tetrakis(2-methyl-2-propanolato)oxotungsten, is an organotungsten compound with the molecular formula C₁₆H₃₆O₅W and a molecular weight of 492.31 g/mol. Typically appearing as white crystals, this compound has a high purity level of 97.5%, verified by elemental analysis. Structurally, tetra-t-butoxide tungsten oxide features a tungsten atom in the +6 oxidation state, coordinated to four tert-butoxide (t-BuO) ligands and a central oxo group. This configuration enhances stability while maintaining reactivity in decomposition or oxidation processes. Sensitive to air and moisture, it requires storage in a tightly sealed container under inert conditions to maintain its integrity.

Applications in Organic Synthesis and Catalysis

Tetra-t-butoxide tungsten oxide is valued in both organic and inorganic synthesis, especially as a precursor for tungsten-containing compounds. The presence of tert-butoxide groups enhances its reactivity, making it highly useful in catalytic reactions within polymerization and advanced material development. Its role as a precursor and catalyst is essential in fields that demand stability paired with high reactivity, such as material science and polymer manufacturing.

Safety and Handling Recommendations

This compound is classified as a flammable solid, necessitating careful handling. Its sensitivity to air and moisture requires that it be stored away from ignition sources in a controlled environment. Standard safety measures, including the use of gloves, eye protection, and ventilation, are recommended to minimize exposure. Due to its volatility, it sublimates at 60°C under reduced pressure (0.01 Torr), which highlights the need for controlled storage and handling.

Industrial and Laboratory Significance

In both industrial and laboratory settings, tetra-t-butoxide tungsten oxide is crucial for producing tungsten oxo compounds and enabling specialized catalytic processes. Its structural composition and reactivity make it particularly effective for complex syntheses, providing stability and adaptability for high-performance applications in material science and catalysis.

Tetra-t-butoxide tungsten oxide is used as a precursor for the preparation of electrochromic tungsten oxide and it doped derivative nanomaterials using sol-gel or vapor deposition methods. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing W2090 contact us at sales@ereztech.com

Safety information

UN 1325
Hazardous class 4.1
Packing group II
Pictograms
Signal word WARNING
Hazard statements H228-H315-H319-H335
Precautionary statements P210-P240-P241-P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378
Transport description Flammable solid, n.o.s. (Tetra-t- butoxide tungsten oxide)
In TSCA registry No (sold for research and development usage only)

First Aid Measures

General advice Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact Wash off with soap and plenty of water. Consult a physician.
Inhalation If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Tetra-t-butoxide tungsten oxide below please contact customer support at sales@ereztech.com

Lot# 019/284

Known applications and external links

With Tetra-t-butoxide tungsten oxide other customers often ask:

Ereztech synthesizes and sells additional W-compounds.

To purchase W2090 contact us at sales@ereztech.com