Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
Synonym: Tris(dipivaloylmethanato)manganese, Shenvi Hydrogenation Catalyst, Mn(TMHD)3, Mn(dpm)3
CAS Number 14324-99-3 | MDL Number MFCD00269825 | EC Number 622-849-1
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) is usually used as a precursor for metal-organic chemical vapor deposition. This non-precious metal catalyst can be utilized to obtain the thermodynamic hydrogenation product of olefins, selectively. It is also can be applied as a catalyst for Intramolecular Diels-Alder reactions; enantioselective synthesis; borylation reactions; hydrohydrazination and hydroazidation as well as for oxidative carbonylation of phenol.Mn-doped anatase TiO2 (Mn: 1.2, 2.4 at%) thin films were grown on Si(100) via atomic layer deposition. The synthesis utilized Ti(OCH(CH3)2)4 and H2O as ALD precursors and Mn(DPM)3 as a dopant source. See links below
Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing MN4993 contact us at sales@ereztech.com
Safety information
| UN | Not regulated |
| Hazardous class | Not regulated |
| Packing group | Not regulated |
| Pictograms |  |
| Signal word | WARNING |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P332 + P313-P337 + P313-P362-P403 + P233-P405 |
| Transport description | NONH for all modes of transport |
| In TSCA registry | No (research and development usage only) |
Certificates of Analysis (CoA)
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External identifiers for Mn(TMHD)3
| Pubchem CID | 11456218 |
| IUPAC Name | (Z)-5-hydroxy-2,2,6,6-tetramethylhept-4-en-3-one;manganese |
| SMILES | CC(C)(C)C(=CC(=O)C(C)(C)C)O[Mn](OC(=CC(=O)C(C)(C)C)C(C)(C)C)OC(=CC(=O)C(C)(C)C)C(C)(C)C |
| InchI Identifier | InChI=1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-; |
| InchI Key | ORZPLLPBZHORSD-LWTKGLMZSA-K |
Known applications and external links
- Ruiqiang Yan, Weiya Huang, Qingfeng Wang, Yinzhu Jiang. Synthesis, characterization, and kinetic study of Mn(DPM)3 used as precursor for MOCVD. Ionics volume 15, pages627–633(2009)
- Meredith C. K. Sellers, Edmund G. Seebauer. Structural and magnetic properties of Mn-doped anatase TiO2 films synthesized by atomic layer deposition. Applied Physics A volume 104, pages583–586(2011)
With Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) other customers often ask:
- Bromopentacarbonylmanganese(I)
- Manganese carbonyl, 98 %
- Manganese(III) acetate dihydrate
- Bis(cyclopentadienyl)manganese
Ereztech synthesizes and sells additional MN-compounds.
To purchase MN4993 contact us at sales@ereztech.com
