Bis(dimethylamino-2-propoxy)copper(II)

Synonym: Bis[1-(dimethylamino)-2-propanolato]copper, Cu(dmap)₂

CAS Number 185827-91-2 | MDL Number MFCD17014025 | EC Number 663-073-3

Product code	CU7912
CAS number	185827-91-2
Assay (purity)	98%+
Purity method	by titration: %Cu=23.0-24.4
Molecular weight	267.86 g/mol
Form	solid
Appearance	dark purple crystals
Melting point	126 to 131°C (258.8 to 267.8°F)
Sensitivity	air, moisture
Molecular formula	CuC10H24N2O2
Linear formula	Cu(C5H12NO)2
Packaging	glassware/metal containers/bubblers

Bis(dimethylamino-2-propoxy)copper(II) is an ALD/CVD precursor for the preparation of Cu, Cu2O, or Cu2S films for electronic applications at temperatures ranging from 135 to 170°C. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing Bis(dimethylamino-2-propoxy)copper(II) contact us at sales@ereztech.com

Safety information

UN	Not regulated
Hazardous class	Not applicable
Packing group	Not applicable
Pictograms
Signal word	WARNING
Hazard statements	H315-H319-H335
Precautionary statements	P231-P222-P305+P351+P338-P403+P233-P422-P501
Transport description	NONH for all modes of transport
In TSCA registry	No (sold for research and development usage only)

First Aid Measures

General advice	Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contact	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contact	Wash off with soap and plenty of water. Consult a physician.
Inhalation	If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed	Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Bis(dimethylamino-2-propoxy)copper(II) below please contact customer support at sales@ereztech.com

Lot# 003/482 Lot# 003/393 Lot# 003/494

External identifiers for Cu(dmap)₂

Pubchem CID	121234236
SMILES	CCC(N(C)C)[O-].CCC(N(C)C)[O-].[Cu+2]
IUPAC Name	copper; 1-(dimethylamino)propan-1-olate
InchI Identifier	InChI=1S/2C5H12NO.Cu/c2*1-4-5(7)6(2)3;/h2*5H,4H2,1-3H3;/q2*-1;+2
InchI Key	AZOFWQDMTKZNMJ-UHFFFAOYSA-N

Known applications and external links

• Sabrina Fadloun, Dean Stephens, Patrice Gergaud, Elisabeth Blanquet, Thierry Mourier, Chris Jones, Steve Burgess, and Amit Rastogi (2018) MOCVD Copper Metallization for High Aspect Ratios TSV 3D Integration. International Symposium on Microelectronics: Fall 2018, Vol. 2018, No. 1, pp. 000718-000727.
• Yunsoo KimChang Gyoun KimTaek-Mo ChungSun Sook LeeKi-Seok AnTaek Seung YangHong Suk Jang Volatile copper aminoalkoxide complex and deposition of copper thin film using same
• Jeong Hwan Han, Yoon Jang Chung, Seong Keun Kim, Bo Keun Park, Hyo-Suk Kim, Chang Gyoun Kim, Taek-Mo Chung Growth of p-Type Tin(II) Monoxide Thin Films by Atomic Layer Deposition from Bis(1-dimethylamino-2-methyl-2propoxy)tin and H2O

With Bis(dimethylamino-2-propoxy)copper(II) other customers often ask:

• Hydrido(triphenylphosphino)copper(I) hexamer
• Bis(N,N’-di-sec-butylacetamidinato)dicopper(I)
• 2,2,6,6-Tetramethyl-3,5-heptanedionate(II)copper

Ereztech synthesizes and sells additional CU-compounds.

To purchase Bis(dimethylamino-2-propoxy)copper(II) contact us at sales@ereztech.com