Iron(III) tert-butoxide dimer
Synonym: Iron(III) t-butoxide, Bis[μ-(tertbutanolato)]tetrakis[(tertbutanolato)]di-iron, Dinuclear iron(III) tert-butoxide complex, [Fe(OtBu)3]2
CAS Number 620945-29-1 | EC Number 230-897-6
Iron(III) tert-butoxide was applied as a single source (both Fe and O) precursor for the deposition of nanocrystalline hematite (Fe2O3) or magnetite (Fe3O4) films by low-pressure CVD. Fe3O4 and Fe2O3 layers deposited on glass substrates were transparent to the visible light, as was determined from the absorption spectra. Nanocrystalline Fe3O4 and Fe2O3 films demonstrated sheet resistance 2.4 kΩ and 2 MΩ, respectively. See link below
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Safety information
UN | 3181 |
Hazardous class | 4.1 |
Packing group | III |
Pictograms | |
Signal word | WARNING |
Hazard statements | H228-H315-H319-H335 |
Precautionary statements | P210-P240-P241-P261-P264-P271-P280-P302 + P352-P304 + P340-P305 + P351 + P338-P312-P332 + P313-P337 + P313-P362-P370 + P378 |
Transport description | Metal salts of organic compounds, flammable, n.o.s. (Iron(III) tert-butoxide dimer) |
In TSCA registry | No (sold for research and development usage only) |
First Aid Measures
General advice | Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area. |
Eye contact | Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. |
Skin contact | Wash off with soap and plenty of water. Consult a physician. |
Inhalation | If breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician. |
If swallowed | Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. |
Certificates of Analysis (CoA)
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External identifiers for [Fe(OtBu)3]2
Pubchem CID | 131856255 |
SMILES | CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].CC(C)(C)[O-].[Fe+3].[Fe+3] |
IUPAC Name | iron(3+); 2-methylpropan-2-olate |
InchI Identifier | InChI=1S/6C4H9O.2Fe/c6*1-4(2,3)5;;/h6*1-3H3;;/q6*-1;2*+3 |
InchI Key | ONEXOPWYODWZIM-UHFFFAOYSA-N |
Known applications and external links
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Ereztech synthesizes and sells additional FE-compounds.
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