Niobium(V) ethoxide

Synonym: Niobium ethanolate, Niobium ethylate, Niobium pentaethoxide, Pentaethoxyniobium, NbOEt

CAS Number 3236-82-6 | MDL Number MFCD00015122  | EC Number 221-795-2

NbOEt Chemical Structure

Product codeNB6826
CAS number3236-82-6
Assay (purity)98.5%+
Metal purity99.99+% – Nb
Purity methodby gravimetric assay: %Nb=28.3-30.5 (after ignition to oxide)
Molecular weight318.21 g/mol
Melting point6 °C (43° F)
Boiling point142 °C (288 °F) @ 5 mmHg
Flash point36 °C (97 °F) – closed cup
Formliquid
Appearanceyellow to gold liquid
Sensitivitymoisture
Molecular formulaC10H25NbO5
Linear formulaNb(OCH2CH3)5
Packagingglassware/metal containers/bubblers

Niobium(V) ethoxide, also known as Niobium pentaethoxide or NbOEt, is an organoniobium compound with the molecular formula C₁₀H₂₅NbO₅ and a molecular weight of 318.21 g/mol. This compound features niobium in a +5 oxidation state, coordinated with five ethoxide groups, forming a stable molecular structure ideal for chemical reactions involving niobium. Niobium(V) ethoxide appears as a yellow to gold liquid with a purity of 99%, confirmed by gravimetric assay. Due to its high sensitivity to moisture, it requires storage under an inert atmosphere.

Applications in Organic and Inorganic Synthesis

Niobium ethoxide is commonly utilized as a niobium precursor in various chemical syntheses and material fabrication. Its reactivity makes it a valuable reagent in producing niobium-based thin films and coatings through sol-gel processes and metal-organic chemical vapor deposition (MOCVD). Additionally, its structure enables controlled hydrolysis reactions, which are essential for creating high-performance niobium oxides and ceramics used in electronics and catalysis.

Precautions for Safe Storage and Handling

Classified with hazard codes H226, H314, and H318, Niobium(V) ethoxide is a flammable and corrosive liquid that can cause severe eye and skin irritation. It should be handled with appropriate protective equipment, including gloves, goggles, and flame-resistant clothing, and used in well-ventilated areas. Due to its moisture sensitivity, storage in sealed, moisture-free containers under an inert gas, such as nitrogen or argon, is essential to prevent degradation.

Industrial and Laboratory Applications

In both industrial and laboratory contexts, Niobium(V) ethoxide plays a crucial role in synthesizing advanced niobium materials and is essential for developing niobium-based ceramics and electronic components. Its use in thin-film deposition, especially in the creation of niobium oxide layers, is highly valued in material science and semiconductor manufacturing. The compound’s unique properties make it indispensable for specialized applications in high-tech industries focused on electronics, catalysis, and advanced material development.

Niobium(V) ethoxide is used for the sol-gel processing of materials containing niobium oxides and mixed metal oxides. It is also used to prepare ferroelectric nanomaterials consisting of oxides of potassium, silicon, and niobium. See links below

Ereztech manufactures and sells this product in small and bulk volumes. Glass ampules, bottles or metal ampules or bubblers are available for packaging. For additional analytical information or details about purchasing NB6826 contact us at sales@ereztech.com

Safety information

UN2924
Hazardous class3(8)
Packing groupIII
PictogramsGHS02
Signal wordDANGER
Hazard statementsH226-H314-H318
Precautionary statementsP210-P231-P232-P233-P240-P241-P242-P243-P261-P264-P240-P241-P242-P243-P260-P264-P280-P301 + P330 + P331-P303 + P353 + P361-P304 + P340-P305 + P351 + P338-P310-P363-P370 + P378
Transport descriptionFlammable liquid, corrosive, n.o.s. (Niobium(V) ethoxide)
In TSCA registryYes

First Aid Measures

General adviceConsult a physician. Show this safety data sheet to the doctor in attendance. Move out of the dangerous area.
Eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Skin contactWash off with soap and plenty of water. Consult a physician.
InhalationIf breathed in, move person into the fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

 

Certificates of Analysis (CoA)

If you don’t see the needed lot of Niobium(V) ethoxide below please contact customer support at sales@ereztech.com

Lot# 019/256 Lot# 019/255 Lot# 019/308 Lot# 026/112 Lot# 015/886 Lot# 015/895

External identifiers for NbOEt

Pubchem CID160675
IUPAC Nameethanolate; niobium(5+)
SMILESCC[O-].CC[O-].CC[O-].CC[O-].CC[O-].[Nb+5]
InchI IdentifierInChI=1S/5C2H5O.Nb/c5*1-2-3;/h5*2H2,1H3;/q5*-1;+5
InchI KeyZTILUDNICMILKJ-UHFFFAOYSA-N

Known applications and external links

With Niobium(V) ethoxide oxide other customers often ask:

Ereztech synthesizes and sells additional NB-compounds.

To purchase NB6826 contact us at sales@ereztech.com